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She has featured in campaigns for: Benetton, Bulgari, Cartier, Clarins, Cortefiel, Dirk Bikkembergs, Fortunoff, Graff, Hewlett Packard/Intel, HS, Intimissimi, John Lewis, Lancaster, La Perla, La Senza, Maidenform, Max Factor, Pantene Pro-V, Passport, Playtex, Rampage, Schwarzkopf, Victoria's Secret, and Wild Orchid.
The day after she arrived, she was rushed to London to shoot a campaign for Pepe Jeans. She lived in Paris for three years, but always returned to Spain because of her family in Barcelona. Lorenzo was signed by the Group modeling agency at a young age.
She finished second in the Elite Look of the Year modeling competition when she was 16.
They announced in September 2013 that they would be having a child.
Puyol announced on 25 January 2014 that their daughter Manuela was born on 24 January 2014.